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James Franck proved atoms take energy in fixed steps

In 1914 James Franck and Gustav Hertz showed electrons lose exactly 4.9 electronvolts to mercury atoms, proving atomic energy is quantised; they won the 1925 Nobel Prize.

James Franck
James Franck · 1882–1964
Person
James Franck
Lived
1882–1964
Field
Atomic physics
From
German-American

The story

In 1913 Niels Bohr proposed that electrons in atoms can only occupy certain fixed energy levels. It was a bold idea, and it needed direct experimental proof.

James Franck, the son of a Jewish banking family from Hamburg, was then a young lecturer at the University of Berlin. His most fruitful collaboration was with Gustav Hertz, with whom he wrote 19 papers. In 1914 the two men built a vacuum tube containing a drop of mercury, heated it to about 115 °C to fill it with a thin vapour, and fired electrons through it towards a metal grid. Slow electrons simply bounced off the mercury atoms. But once an electron had enough energy, it would lose exactly 4.9 electronvolts in a collision, never more and never less. They presented these results to the German Physical Society on 24 April 1914.

In a second paper that May, they showed that the mercury then glowed with ultraviolet light, at a wavelength of about 254 nanometres, which corresponded precisely to that amount of energy. This was clear evidence that atoms absorb energy only in discrete packets, as Bohr’s model required. At first Franck and Hertz did not realise the connection; in his Nobel lecture Franck admitted they had not even mentioned Bohr’s theory. Their final joint paper, in December 1918, reconciled their results with it. After Franck later presented the findings, Albert Einstein is said to have remarked that it was so lovely it made you cry.

Franck and Hertz received the 1925 Nobel Prize in Physics, presented on 10 December 1926, for their discovery of the laws governing the impact of an electron upon an atom. It was the first electrical measurement to show clearly the quantum nature of atoms.

Their experiment is still performed by physics students around the world as the classic demonstration of quantum energy levels, using teaching tubes built on the same plan. Franck’s later work on how excited atoms hold and pass on energy also produced results that proved important in the development of the laser.

Why it matters

The experiment helped establish quantum theory, the physics behind lasers, LEDs, fluorescent lamps and modern electronics.

About James Franck

Nobel physicist whose electron-collision experiment proved atoms have quantised energy levels; he resigned in protest in 1933 and later led the Franck Report against a surprise atomic attack.

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James Franck
1882–1964 · Atomic physics
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